Here are a couple of tidbits from this link on emission faq
HC tells us how much of the available fuel was NOT burned. (High HC = sooty smoke) Low HC is good (no soot). High HC is the result of incomplete burning of the fuel mixture. High HC can result from anything causing incomplete combustion.
Catalytic converters need heat (about 550 degrees F) and oxygen to work properly. At idle, a properly tuned engine will produce little oxygen, and exhaust termperatures may drop to well below 550 degrees F. If you take the catalyst out of the picture by allowing it to cool down, don't forget to relight it before final emission testing. Many cars which fail emissions tests do so because the catalyst isn't up to temperature, or doesn't have enough oxygen to do its job. When testing for catalyst efficiency, start and fully warm the engine. Then run it at 2500 RPM for two minutes.
more than you ever want to know about emissions
Dinan chip, Bilstein sports w H&R, RD sways, RD strut brace, 750 bushings, Zimmermans/MetalMasters, O.E. M Pars, Eisenmann muffler